Dreamweaver Collaboration Help

Hello All,

I am new to Web Designing and Web Developing. Can anybody tell me how can I
collaborate Visual Studio .Net 2003 and Dreamweaver MX together to build a
web-site. I can make a normal web-site with fairly decent functionality using
Visual Studio but I dont like the fact I cant design a great looking interface.

Any help will be appreciated. Any links on web or some other free sources and
tutorials. 

Thanks in advance